Product ID:CLEANERS-WATER BASED, TWIN ETCH METAL CLEANER
MSDS Date:08/01/1991
FSC:8030
NIIN:00N022902
MSDS Number: BXSLZ

MARTIN-SENOUR CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2283

Cage: 16772

MARTIN-SENOUR CO THE DIV SHERWIN-WILLIAMS CO

CHICAGO, IL 60608-5724 US

Cage: 16772

0.6

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 12%

OSHA PEL 50 PPM, S

ACGIH TLV: 25 PPM, S

PHOSPHORIC ACID (SARA 313) (CERCLA)

CAS: 7664-38-2

RTECS: TB6300000

Fraction By Weight: 24%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 3 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 61.9%

OSHA PEL N/K

ACGIH TLV: N/K

1.13 LBS/GAL (TOTAL); VOC LESS

RTECS: 9999999VO

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRITATION OF EYES, SKIN &
RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME
OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS & POSSIBLY DEATH.
CHRONIC: ANIMAL STUDIES HAVE CLEARLY SHO WN DOSE-RELATED ADVERSE
EFFECTS ON CNS,HEMATOPOIETIC TISSUES, BLOOD, KIDNEYS & LIVER
ASSOCIATED W/THE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: ADMIN OF 2-BUTOXYETHANOL. (EXTRACTED
FROM DHHS (NIOSH) PUBLICATION NO. 90-118) . PROLONGED OVEREXP TO
SOLVENT INGREDIENTS MAY CAUSE ADVERSE EFFECTS TO LIVER, URINARY &
BLOOD-FORMING SY STEMS. REPORTS HAVE ASSOCIATED REPEATED& PROLONGED
OVEREXP TO SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL: LEAVE AREA & GET FRESH AIR. IF PROBLEMS REMAIN OR
OCCUR LATER IMMEDIATELY GET MEDICAL ATTENTION. SKIN: WASH AFFECTED
AREA THOROUGHLY WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING &
LAUNDER BE FORE REUSE. EYES: FLUSH EYES WITH LARGEAMOUNTS OF WATER
FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: GET MEDICAL
ATTENTION.

Flash Point:>199F,>93C
Lower Limits:0.75
Upper Limits:12.7%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF.
WATER MAY BE USED TO COOL CLSD (SUPDAT)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTNR CLSD WHEN NOT IN USE.
TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT
TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING
VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES. WASH HANDS
AFTER USING.

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP
APPRVD BY NIOSH/MSHA. WHEN SANDING, WIREBRUSHING, ABRADING,
BURNING, WELDING DRIED FILM, WEAR RESP APPRVD BY NIOSH/MSHA
(SUPDAT)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED
BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94,107,108.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EYEWASH FOUNTAIN & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLOS
WHEN EXPOSED TO EXTREME HEAT. RESP PROT: FOR PROTECTION AGAINST
NON-VOLATILE MATERIALS.

Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.0-1.2
pH:0.9
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:86-100

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, PHOSPHORIC ACID FUMES, OXIDES OF PHOSPHORUS.

Waste Disposal Methods:WASTE FROM THESE PRODUCTS IS NOT HAZARDOUS AS
DEFINED UNDER RCRA 40 CFR 261. INCINERATE IN APPROVED FACILITY. DO
NOT INCINERATE CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS REGARDING POLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.